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CAS Number: | 68916-04-1 |
FDA UNII: | 9TLV70SV6I |
Category: | flavor and fragrance agents |
IUPAC Name: | bitter orange peel oil brazil |
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FEMA Number: | 2823 bitter orange peel oil brazil |
FDA: | No longer provide for the use of these seven synthetic flavoring substances |
FDA Mainterm (SATF): | 68916-04-1 ; ORANGE PEEL, BITTER, OIL (CITRUS AURANTIUM L.) |
FDA Regulation: | |
FDA PART 182 -- SUBSTANCES GENERALLY RECOGNIZED AS SAFE Subpart A--General Provisions Sec. 182.20 Essential oils, oleoresins (solvent-free), and natural extractives (including distillates). |
Appearance: | pale yellow to yellow clear liquid (est) |
Food Chemicals Codex Listed: | No |
Specific Gravity: | 0.84500 to 0.85100 @ 25.00 °C. |
Pounds per Gallon - (est).: | 7.031 to 7.081 |
Refractive Index: | 1.46900 to 1.47800 @ 20.00 °C. |
Optical Rotation: | +88.00 to +98.00 |
Flash Point: | 118.00 °F. TCC ( 47.78 °C. ) |
Shelf Life: | 12.00 month(s) or longer if stored properly. |
Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
Soluble in: | |
alcohol | |
fixed oils | |
paraffin oil, slightly cloudy | |
water, 4.581 mg/L @ 25 °C (est) | |
Insoluble in: | |
water | |
Stability: | |
bath foam | |
hair spray | |
lipstick | |
soap |
CosIng: | cosmetic data |
Cosmetic Uses: | fragrance skin conditioning tonic |
Absolute Cosmetic Essentials |
Orange, Bitter |
Berjé |
Orange Oil Bitter Brazil |
Media |
Bontoux |
ORANGE BLOOD MD ESSENTIAL OIL |
Bristol Botanicals |
Orange Bitter essential oil Citrus aurantium amara |
Charabot |
Orange bigarade oil 100% Pure & Natural, Kosher Odor: zesty, aldehydic, green, mandarin |
Citrus and Allied Essences |
Oil Bitter Orange Brazilian C.P. FCC |
Market Report |
Ernesto Ventós |
ORANGE OIL BITTER Odor: ORANGE PEEL, CITRICO, FRESCO |
Excellentia International |
Orange Oil Bitter |
Fleurchem |
orange bitter oil |
George Uhe Company |
bitter Orange Oil Brazil Available in FCC |
IFF |
Orange Bigarade Oil MD SCFC Odor: Enhanced fruity, zesty orange note. Good balance between the aldehydic character and the fruity sweetness of the oil |
Indukern F&F |
ORANGE OIL BITTER BRAZIL Odor: CHARACTERISTIC, CITRUS, FRESH, BITTER |
Kanta Enterprises |
Orange Bitter Brasil Oil |
Lionel Hitchen |
Orange Oil Bitter 2-fold to10-fold |
Lluch Essence |
ORANGE BITTER BRAZIL OIL |
Lluch Essence |
ORANGE BITTER IVORY COAST OIL |
Penta International |
ORANGE OIL BITTER |
PerfumersWorld |
Orange Oil Bitter Odor: orange aldehydic peel fresh leaf Use: Blends-well-with - +Clary Sage +Labdanum +Oakmoss +Rosemary +Abies Sibirica |
Plants Power |
bitter Orange Oil Spain Odor: semi-sweet citrus, fresh yet bitter with a woody-herbaceous undertone Use: Bitter orange is good for digestive problems such as constipation and flatulence, relieving stress and anxiety, fighting colds, and soothing mouth ulcers. It is used in perfumery, cosmetics, bath and body oils, and flavouring chocolate and confectionery. |
R C Treatt & Co Ltd |
Orange Bitter Oil Halal, Kosher |
R C Treatt & Co Ltd |
Orange Bitter W.I. 5-Fold Halal, Kosher |
R C Treatt & Co Ltd |
Orange Bitter Wi Halal, Kosher |
R C Treatt & Co Ltd |
Orange Oil Bitter Brazilian Halal, Kosher |
Reincke & Fichtner |
Orange Oil bitter organic NOP |
Reincke & Fichtner |
Orange Oil bitter |
Robertet |
Orange bigarade oil 100% Pure & Natural, Kosher Odor: zesty, aldehydic, green, mandarin |
Seasons and Harvest / Crop calendar |
The Lermond Company |
ORANGE OIL, BITTER NATURAL |
The Perfumery |
Orange oil, Bitter, Brazil Odor: characteristic Use: Bitter Orange oil's bitter, citrus, and characteristic aroma comes from the cold pressed peels of the Citrus aurantium fruit; the same tree Neroli oil and Orange Blossom Absolute originate from. Bitter Orange oil is used in often in aromatherapy in many of the same ways Sweet Orange oil is used. In perfumery Bitter Orange oil adds a tart, fresh, citrus top note that can be found in many perfume and aromatherapy blends. |
Ultra International |
Bitter Orange Oil Brazil |
Crop Calendar |
Zanos |
ORANGE BITTER |
European information : | |
Most important hazard(s): | |
Xi - Irritant | |
R 10 - Flammable. R 38 - Irritating to skin. R 43 - May cause sensitisation by skin contact. S 02 - Keep out of the reach of children. S 16 - Keep away from sources of ignition - No Smoking. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 - Wear suitable gloves and eye/face protection. | |
Hazards identification | |
Classification of the substance or mixture | |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
Flammable liquids (Category 3), H226 Skin irritation (Category 2), H315 | |
GHS Label elements, including precautionary statements | |
Pictogram | ![]() ![]() |
Signal word | Warning |
Hazard statement(s) | |
H226 - Flammable liquid and vapour H315 - Causes skin irritation | |
Precautionary statement(s) | |
P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/…/equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P264 - Wash skin thouroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P321 - Specific treatment (see supplemental first aid instructions on this label). P332 + P313 - IF SKIN irritation occurs: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P403 + P235 - Store in a well-ventilated place. Keep cool. P501 - Dispose of contents/ container to an approved waste disposal plant. | |
Oral/Parenteral Toxicity: | |
oral-rat LD50 > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 12, Pg. 735, 1974. | |
Dermal Toxicity: | |
skin-rabbit LD50 > 10000 mg/kg Food and Cosmetics Toxicology. Vol. 12, Pg. 735, 1974. | |
Inhalation Toxicity: | |
Not determined |
Category: | |||
flavor and fragrance agents | |||
RIFM Fragrance Material Safety Assessment: Search | |||
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
IFRA Critical Effect: | |||
Phototoxicity | |||
IFRA fragrance material specification: | |||
Where the bergapten (5-methoxypsoralen) content of all relevant oils present in a compound has been determined, it is recommended that for applications on areas of skin exposed to sunshine, excluding bath preparations, soaps and other products which are washed off the skin, the total level of bergapten in the consumer products should not exceed 0.0015% (15 ppm). This is equivalent to 0.0075% (75 ppm) in a fragrance compound used at 20% in the consumer product.Where the level of bergapten has not been determined by appropriate methods, the limits specified in the guidelines on individual oils should apply.In those cases, where such oils are used in combination with other phototoxic ingredients, the additive effect has to be taken into consideration and the use levels have to be reduced accordingly. The sum of the concentrations of all phototoxic fragrance ingredients, expressed in % of their recommended maximum level in the consumer product, shall not exceed 100. | |||
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only) | |||
citral | Max. Found: 0.1 % and Reason: Sensitization | ||
citronellol | Max. Found: trace to <0.10 % and Reason: Sensitization | ||
geraniol | Max. Found: 0.04 % and Reason: Sensitization | ||
perillaldehyde | Max. Found: 0.02 % and Reason: Sensitization | ||
View the IFRA Standard | |||
View IFRA Standards Library for complete information. | |||
Please review Amendment 49 IFRA documentation for complete information. | |||
IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%): | |||
Category 1: Products applied to the lips | |||
1.25 % | |||
Category 2: Products applied to the axillae | |||
1.25 % | |||
Category 3: Products applied to the face/body using fingertips | |||
1.25 % | |||
Category 4: Products related to fine fragrance | |||
1.25 % | |||
Category 5: Products applied to the face and body using the hands (palms), primarily leave-on | |||
Category 5A: Body lotion products applied to the body using the hands (palms), primarily leave-on | |||
1.25 % | |||
Category 5B: Face moisturizer products applied to the face using the hands (palms), primarily leave-on | |||
1.25 % | |||
Category 5C: Hand cream products applied to the hands using the hands (palms), primarily leave-on | |||
1.25 % | |||
Category 5D: Baby Creams, baby Oils and baby talc | |||
1.25 % | |||
Category 6: Products with oral and lip exposure | |||
1.25 % | |||
Category 7: Products applied to the hair with some hand contact | |||
Category 7A: Rinse-off products applied to the hair with some hand contact | |||
No Restriction % | |||
Category 7B: Leave-on products applied to the hair with some hand contact | |||
1.25 % | |||
Category 8: Products with significant anogenital exposure | |||
1.25 % | |||
Category 9: Products with body and hand exposure, primarily rinse off | |||
No Restriction % | |||
Category 10: Household care products with mostly hand contact | |||
Category 10A: Household care excluding aerosol products (excluding aerosol/spray products) | |||
No Restriction % | |||
Category 10B: Household aerosol/spray products | |||
1.25 % | |||
Category 11: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate | |||
Category 11A: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure | |||
No Restriction % | |||
Category 11B: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure | |||
1.25 % | |||
Category 12: Products not intended for direct skin contact, minimal or insignificant transfer to skin | |||
No Restriction | |||
Notes: | |||
IFRA FLAVOR REQUIREMENTS: | |||
Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards. | |||
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library | |||
publication number: 3 | |||
Click here to view publication 3 | |||
average usual ppm | average maximum ppm | ||
baked goods: | - | 110.00000 | |
beverages(nonalcoholic): | - | 67.00000 | |
beverages(alcoholic): | - | 4.00000 | |
breakfast cereal: | - | - | |
cheese: | - | - | |
chewing gum: | - | 500.00000 | |
condiments / relishes: | - | - | |
confectionery froastings: | - | - | |
egg products: | - | - | |
fats / oils: | - | - | |
fish products: | - | - | |
frozen dairy: | - | 71.00000 | |
fruit ices: | - | 71.00000 | |
gelatins / puddings: | - | 300.00000 | |
granulated sugar: | - | - | |
gravies: | - | - | |
hard candy: | - | 150.00000 | |
imitation dairy: | - | - | |
instant coffee / tea: | - | - | |
jams / jellies: | - | - | |
meat products: | - | - | |
milk products: | - | - | |
nut products: | - | - | |
other grains: | - | - | |
poultry: | - | - | |
processed fruits: | - | - | |
processed vegetables: | - | - | |
reconstituted vegetables: | - | - | |
seasonings / flavors: | - | - | |
snack foods: | - | - | |
soft candy: | - | - | |
soups: | - | - | |
sugar substitutes: | - | - | |
sweet sauces: | - | - |
European Food Safety Authority (EFSA) reference(s): |
Safety and efficacy of a feed additive consisting of a flavonoid-rich dried extract of Citrus � aurantium L. fruit (bitter orange extract) for use in all animal species (FEFANA asbl) View page or View pdf |
EPI System: View |
AIDS Citations:Search |
Cancer Citations:Search |
Toxicology Citations:Search |
EPA Substance Registry Services (TSCA):68916-04-1 |
EPA ACToR:Toxicology Data |
EPA Substance Registry Services (SRS):Registry |
National Institute of Allergy and Infectious Diseases:Data |
WISER:UN 1993 |
WGK Germany:2 |
citrus aurantium l. peel oil bitter brazil |
Chemidplus:0068916041 |
citrus aurantium l. peel oil bitter brazil | |
Canada Domestic Sub. List: | 68916-04-1 |
Pubchem (sid): | 135326045 |
FDA Substances Added to Food (formerly EAFUS): | View |
Export Tariff Code: | 3301.12.0000 |
Typical G.C. | |
Wikipedia: | View |
FAO: | BASIC PRINCIPLES OF STEAM DISTILLATION |
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