| 2D: |  |
|---|---|
| 3D: | |
| CAS Number: | 6658-48-6 |
| ECHA EC Number: | 229-695-0 |
| FDA UNII: | Search |
| Category: | fragrance agents |
| IUPAC Name: | cyclamen homoaldehyde |
| InChI : | InChI=1/C14H20O/c1-11(2)8-13-4-6-14(7-5-13)9-12(3)10-15/h4-7,10-12H,8-9H2,1-3H3 |
| Std.InChI: | InChI=1S/C14H20O/c1-11(2)8-13-4-6-14(7-5-13)9-12(3)10-15/h4-7,10-12H,8-9H2,1-3H3 |
| InChIKey : | YLIXVKUWWOQREC-UHFFFAOYAF |
| Std.InChIKey: | YLIXVKUWWOQREC-UHFFFAOYSA-N |
| SMILES : | CC(C)CC1=CC=C(C=C1)CC(C)C=O |
| Molar Refractivity : | 63.98 ± 0.3 cm3 (est) |
| Parachor : | 523.2 ± 4.0 cm3 (est) |
| Index of Refraction : | 1.495 ± 0.02 (est) |
| Surface Tension : | 32.4 ± 3.0 dyne/cm (est) |
| Density : | 0.932 ± 0.06 g/cm3 (est) |
| Polarizability : | 25.36 ± 0.5 10-24cm3 (est) |
| Fragrance Demo Formulas | |
| Appearance: | colorless clear liquid (est) |
| Assay: | 96.00 to 100.00 |
| Food Chemicals Codex Listed: | No |
| Boiling Point: | 285.00 to 286.00 °C. @ 760.00 mm Hg |
| Vapor Pressure: | 0.003000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 273.00 °F. TCC ( 133.89 °C. ) |
| logP (o/w): | 4.034 (est) |
| Soluble in: | |
| alcohol | |
| water, 7.299 mg/L @ 25 °C (est) | |
| Stability: | |
| alcoholic fine fragrances - good | |
| antiperspirants - good | |
| concentrated fabric softeners - good | |
| hypochlorite bleach - poor | |
| liquid detergent - good | |
| perborate powder detergent - good | |
| soaps - good | |
| toiletry applications - good | |
| CosIng: | cosmetic data |
| Cosmetic Uses: | perfuming agents |
| BOC Sciences |
| For experimental / research use only. |
| Benzenepropanal, a-methyl-4-(2-methylpropyl)- |
| Creatingperfume.com |
| Silvial® (Givaudan) Odor: Powerful, Floral, Muguet, Fresh |
| Givaudan |
| Silvial® Odor: Powerful, Floral, Muguet, Fresh Use: Silvial is a powerful, vibrant muguet ingredient with a slight citrus undertone and a fresh, aldehydic touch that is used in perfumery in the same way as related muguet products. |
| Lluch Essence |
| SILVIAL |
| Moellhausen |
| SILVIAL |
| Pell Wall Perfumes |
| Silvial Odor: Floral-muguet, fresh-marine, aldehydic, green, balsamic Use: Arctander thought the material had potential for wider use: “The title aldehyde, commercially available for some years, has some of the advantages of Cyclamen aldehyde, and some of those of Lilial (Bucinal), its tertiary-Butyl-isomer. It is undoubtedly more versatile than Cyclamen aldehyde, and the perfumer can enjoy using much higher concentrations of this aldehyde, without producing overly green-vegetable notes, etc” |
| Penta International |
| P-ISOBUTYL-ALPHA-METHYLHYDROCINNAMALDEHYDE |
| Perfumery Laboratory |
| SILVIAL Givaudan Odor: Flower (lily), fresh sea, aldehyde, with a tinge of green |
| The Perfumers Apprentice |
| Silvial (G) Odor: vibrant muguet ingredient with a slightly citrus aspect and a fresh, aldehydic touch |
| Vigon International |
| Silvial Odor: Powerful, Floral, Muguet, Fresh |
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| Skin corrosion/irritation (Category 3), H316 Skin sensitisation (Category 1), H317 Reproductive toxicity (Category 2), H361 Acute aquatic toxicity (Category 2), H401 Chronic aquatic toxicity (Category 2), H411 | |
| GHS Label elements, including precautionary statements | |
| Pictogram |    |
| Signal word | Warning |
| Hazard statement(s) | |
| H316 - Causes mild skin irritation H317 - May cause an allergic skin reaction H361 - Suspected of damaging fertility or the unborn child H401 - Toxic to aquatic life H411 - Toxic to aquatic life with long lasting effects | |
| Precautionary statement(s) | |
| P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash skin thouroughly after handling. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302 + P352 - IF ON SKIN: wash with plenty of soap and water. P308 + P313 - IF exposed or concerned: Get medical advice/attention. P333 + P313 - IF SKIN irritation or rash occurs: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P391 - Collect spillage. Hazardous to the aquatic environment P405 - Store locked up. P501 - Dispose of contents/ container to an approved waste disposal plant. | |
| Oral/Parenteral Toxicity: | |
| Not determined | |
| Dermal Toxicity: | |
| Not determined | |
| Inhalation Toxicity: | |
| Not determined | |
| Category: | |||
| fragrance agents | |||
| RIFM Fragrance Material Safety Assessment: Search | |||
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
| IFRA Critical Effect: | |||
| Dermal sensitization and systemic toxicity | |||
| View the IFRA Standard | |||
| View IFRA Standards Library for complete information. | |||
| Please review Amendment 49 IFRA documentation for complete information. | |||
| IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%): | |||
| Category 1: Products applied to the lips | |||
| 0.08 % | |||
| Category 2: Products applied to the axillae | |||
| 0.053 % | |||
| Category 3: Products applied to the face/body using fingertips | |||
| 0.80 % | |||
| Category 4: Products related to fine fragrance | |||
| 0.99 % | |||
| Category 5: Products applied to the face and body using the hands (palms), primarily leave-on | |||
| Category 5A: Body lotion products applied to the body using the hands (palms), primarily leave-on | |||
| 0.25 % | |||
| Category 5B: Face moisturizer products applied to the face using the hands (palms), primarily leave-on | |||
| 0.25 % | |||
| Category 5C: Hand cream products applied to the hands using the hands (palms), primarily leave-on | |||
| 0.25 % | |||
| Category 5D: Baby Creams, baby Oils and baby talc | |||
| 0.083 % | |||
| Category 6: Products with oral and lip exposure | |||
| 0.080 % | |||
| Category 7: Products applied to the hair with some hand contact | |||
| Category 7A: Rinse-off products applied to the hair with some hand contact | |||
| 0.72 % | |||
| Category 7B: Leave-on products applied to the hair with some hand contact | |||
| 0.72 % | |||
| Category 8: Products with significant anogenital exposure | |||
| 0.083 % | |||
| Category 9: Products with body and hand exposure, primarily rinse off | |||
| 1.90 % | |||
| Category 10: Household care products with mostly hand contact | |||
| Category 10A: Household care excluding aerosol products (excluding aerosol/spray products) | |||
| 1.90 % | |||
| Category 10B: Household aerosol/spray products | |||
| 5.40 % | |||
| Category 11: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate | |||
| Category 11A: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure | |||
| 0.083 % | |||
| Category 11B: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure | |||
| 0.083 % | |||
| Category 12: Products not intended for direct skin contact, minimal or insignificant transfer to skin | |||
| No Restriction | |||
| Notes: | |||
| IFRA FLAVOR REQUIREMENTS: | |||
Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards. | |||
| Recommendation for cyclamen homoaldehyde flavor usage levels up to: | |||
| not for flavor use. | |||
| EPI System: View |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA Substance Registry Services (TSCA):6658-48-6 |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :110914 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:2 |
| 2-methyl-3-[4-(2-methylpropyl)phenyl]propanal |
| Chemidplus:0006658486 |
| Leffingwell: | Chirality or Article |
| 2-methyl-3-[4-(2-methylpropyl)phenyl]propanal | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 6658-48-6 |
| Pubchem (cid): | 110914 |
| Pubchem (sid): | 135067153 |
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| HMDB (The Human Metabolome Database): | Search |
| ChemSpider: | View |
| not found in nature |
| benzenepropanal, a-methyl-4-(2-methylpropyl)- | |
| para-iso | butyl-alpha-methyl hydrocinnamaldehyde |
| 3-(4-iso | butylphenyl)-2-methylpropanal |
| 3-(p- | cumenyl)-2-methyl propionaldehyde |
| 3-(para- | cumenyl)-2-methyl propionaldehyde |
| cyclamen homoaldehyde | |
| 2- | methyl-3-(4-(2-methyl propyl)phenyl) propanal |
| 2- | methyl-3-[4-(2-methylpropyl)phenyl]propanal |
| alpha- | methyl-4-(2-methyl propyl) benzene propanal |
| a- | methyl-4-(2-methylpropyl)benzenepropanal |
| alpha- | methyl-4-(2-methylpropyl)benzenepropanal |
| a- | methyl-4-(2-methylpropyl)benzenepropionaldehyde |
| rhodial | |
| silvial (Givaudan) | |
| suzaral (Takasago) |
| None found yet. Try the PubMed Search. |
