| 2D: |  |
|---|---|
| 3D: | |
| CAS Number: | 18172-67-3 |
| ECHA EC Number: | 242-060-2 |
| FDA UNII: | AFN153A7SU |
| Category: | flavor and fragrance agents |
| IUPAC Name: | laevo-beta-pinene |
| InChI : | InChI=1/C10H16/c1-7-4-5-8-6-9(7)10(8,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9-/m0/s1 |
| Std.InChI: | InChI=1S/C10H16/c1-7-4-5-8-6-9(7)10(8,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9-/m0/s1 |
| InChIKey : | WTARULDDTDQWMU-IUCAKERBBX |
| Std.InChIKey: | WTARULDDTDQWMU-IUCAKERBSA-N |
| SMILES : | CC1(C2CCC1C(=C)C2)C |
| MDL: | MFCD00001345 |
| Molar Refractivity : | 43.76 ± 0.4 cm3 (est) |
| Parachor : | 349.0 ± 6.0 cm3 (est) |
| Index of Refraction : | 1.483 ± 0.03 (est) |
| Surface Tension : | 27.0 ± 5.0 dyne/cm (est) |
| Density : | 0.88 ± 0.1 g/cm3 (est) |
| Polarizability : | 17.34 ± 0.5 10-24cm3 (est) |
| Google Scholar: | Search |
| Google Books: | Search |
| Google Scholar: with word "volatile" | Search |
| Google Scholar: with word "flavor" | Search |
| Google Scholar: with word "odor" | Search |
| Perfumer and Flavorist: | Search |
| Google Patents: | Search |
| US Patents: | Search |
| EU Patents: | Search |
| Pubchem Patents: | Search |
| PubMed: | Search |
| NCBI: | Search |
| FEMA Number: | 2903 L-beta-pinene |
| FDA: | No longer provide for the use of these seven synthetic flavoring substances |
| Appearance: | colorless clear liquid (est) |
| Assay: | 97.00 to 100.00 |
| Food Chemicals Codex Listed: | Yes |
| Specific Gravity: | 0.86700 to 0.87100 @ 25.00 °C. |
| Pounds per Gallon - (est).: | 7.214 to 7.248 |
| Refractive Index: | 1.47600 to 1.48200 @ 20.00 °C. |
| Optical Rotation: | -15.00 to -30.00 |
| Melting Point: | -61.00 °C. @ 760.00 mm Hg |
| Boiling Point: | 165.00 to 167.00 °C. @ 760.00 mm Hg |
| Vapor Pressure: | 2.399000 mmHg @ 25.00 °C. (est) |
| Vapor Density: | 4.7 ( Air = 1 ) |
| Flash Point: | 91.00 °F. TCC ( 32.78 °C. ) |
| logP (o/w): | 4.239 (est) |
| Soluble in: | |
| alcohol | |
| water, 7.061 mg/L @ 25 °C (est) | |
| Insoluble in: | |
| water | |
| CosIng: | cosmetic data |
| Cosmetic Uses: | perfuming agents |
| Advanced Biotech |
| BETA PINENE NATURAL |
| Aurochemicals |
| PINENE BETA (1S), Natural |
| Axxence Aromatic |
| beta-PINENE Natural Kosher |
| Sustainability |
| BOC Sciences |
| For experimental / research use only. |
| (1S)-(-)-β-Pinene |
| ExtraSynthese |
| For experimental / research use only. |
| (-)-beta-Pinene (GC) ≥96% |
| Lluch Essence |
| BETA-PINENE NATURAL 97% LAEVO |
| Pell Wall Perfumes |
| Pinene beta, natural isolate Odor: Dry-woody, fresh-pine, watery, clean, resinous Use: This product is the natural isolate of beta Pinene extracted from mint oil and as such is the laevo form. See also our synthetic beta Pinene for a slightly cheaper, racemic option. |
| Penta International |
| (-)-B-PINENE |
| Prodasynth |
| BETA PINENE, NATURAL (> 98%) Odor: DRY, WOODY, PINEY, RESINOUS |
| Prodasynth |
| BETA PINENE (> 97%) Odor: DRY, WOODY, PINEY, RESINOUS |
| Reincke & Fichtner |
| laevo-beta-Pinene |
| Santa Cruz Biotechnology |
| For experimental / research use only. |
| (-)-β-Pinene |
| Sigma-Aldrich |
| (-)-b-Pinene, ≥97%, FCC, FG Odor: woody |
| Certified Food Grade Products |
| SRS Aromatics |
| BETA PINENE (LAEVO) |
| Takasago |
| Pinene Beta Biobased 100% Odor: Warm, resinous, refreshing pine-like Use: Used in flavor formulation with citrus or tropical fruit notes. |
| The Fragrance Museum |
| TCI AMERICA |
| For experimental / research use only. |
| (-)-βPinene >94.0%(GC) |
| Preferred SDS: View | |
| European information : | |
| Most important hazard(s): | |
| Xn N - Harmful, Dangerous for the environment. | |
| R 10 - Flammable. R 22 - Harmful if swallowed. R 36/38 - Irritating to skin and eyes. R 50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S 02 - Keep out of the reach of children. S 16 - Keep away from sources of ignition - No Smoking. S 20/21 - When using do not eat, drink or smoke. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 - Wear suitable gloves and eye/face protection. S 60 - This material and its container must be disposed of as hazardous waste. S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet. S 62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. | |
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| None found. | |
| GHS Label elements, including precautionary statements | |
| Pictogram | |
| Hazard statement(s) | |
| None found. | |
| Precautionary statement(s) | |
| None found. | |
| Human Experience: | |
| 12 % solution: no irritation or sensitization. | |
| Oral/Parenteral Toxicity: | |
| oral-rat LD50 4700 mg/kg FCTXAV 16,859,1978 | |
| Dermal Toxicity: | |
| Not determined | |
| Inhalation Toxicity: | |
| Not determined | |
| Category: | |||
| flavor and fragrance agents | |||
| RIFM Fragrance Material Safety Assessment: Search | |||
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
| Recommendation for laevo-beta-pinene usage levels up to: | |||
| 12.0000 % in the fragrance concentrate. | |||
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library | |||
| publication number: 3 | |||
| Click here to view publication 3 | |||
| average usual ppm | average maximum ppm | ||
| baked goods: | 48.00000 | 600.00000 | |
| beverages(nonalcoholic): | 0.05000 | 16.00000 | |
| beverages(alcoholic): | - | - | |
| breakfast cereal: | - | - | |
| cheese: | - | - | |
| chewing gum: | - | - | |
| condiments / relishes: | - | - | |
| confectionery froastings: | - | - | |
| egg products: | - | - | |
| fats / oils: | - | - | |
| fish products: | - | - | |
| frozen dairy: | - | 64.00000 | |
| fruit ices: | - | 64.00000 | |
| gelatins / puddings: | - | - | |
| granulated sugar: | - | - | |
| gravies: | - | - | |
| hard candy: | 48.00000 | 600.00000 | |
| imitation dairy: | - | - | |
| instant coffee / tea: | - | - | |
| jams / jellies: | - | - | |
| meat products: | - | - | |
| milk products: | - | - | |
| nut products: | - | - | |
| other grains: | - | - | |
| poultry: | - | - | |
| processed fruits: | - | - | |
| processed vegetables: | - | - | |
| reconstituted vegetables: | - | - | |
| seasonings / flavors: | - | - | |
| snack foods: | - | - | |
| soft candy: | - | - | |
| soups: | - | - | |
| sugar substitutes: | - | - | |
| sweet sauces: | - | - | |
| EPI System: View |
| Chemical Carcinogenesis Research Information System:Search |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA Substance Registry Services (TSCA):18172-67-3 |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :440967 |
| National Institute of Allergy and Infectious Diseases:Data |
| WISER:UN 2319 |
| WGK Germany:3 |
| (1S,5S)-7,7-dimethyl-4-methylidenebicyclo[3.1.1]heptane |
| Chemidplus:0018172673 |
| RTECS:DT5077000 for cas# 18172-67-3 |
| (1S,5S)-7,7-dimethyl-4-methylidenebicyclo[3.1.1]heptane | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 18172-67-3 |
| Pubchem (cid): | 440967 |
| Pubchem (sid): | 134993351 |
| Pherobase: | View |
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| CHEBI: | View |
| CHEMBL: | View |
| KEGG (GenomeNet): | C06307 |
| HMDB (The Human Metabolome Database): | HMDB36559 |
| FooDB: | FDB015463 |
| Export Tariff Code: | 2902.19.0050 |
| VCF-Online: | VCF Volatile Compounds in Food |
| ChemSpider: | View |
| Wikipedia: | View |
| FR | balsam |
| FL | candy |
| FL | carrot |
| FR | citrus |
| FR | cologne |
| FL/FR | coriander |
| FL | cream ice cream |
| FR | cumin oil replacer |
| dry | |
| FR | earth |
| fir | |
| FR | green |
| FR | hay new mown hay |
| FR | herbal |
| FL/FR | hyssop |
| FR | juniper berry |
| FR | lavender |
| FR | lemon |
| FR | lime |
| FR | mint |
| FR | nutmeg |
| FR | orange |
| FR | pepper |
| FR | petitgrain |
| FR | pine |
| FR | pine forest |
| resin | |
| FR | wintergreen |
| almond Search Trop Picture | |
| bay laurel fruit oil Search Trop Picture | |
| bay laurel seed oil Search Trop Picture | |
| carrot Search Trop Picture | |
| coriander Search Trop Picture | |
| cumin Search Trop Picture | |
| hyssop Search Trop Picture | |
| lemon Search Trop Picture | |
| nutmeg seed Search Trop Picture | |
| orange fruit juice Search Trop Picture | |
| sage Search Trop Picture | |
| turpentine Search Picture |
| bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene-, (1S,5S)- | |
| (1S,5S)-6,6- | dimethyl-2-methylene bicyclo(3.1.1)heptane |
| (1S)-6,6- | dimethyl-2-methylene bicyclo(3.1.1)heptane |
| laevo-6,6- | dimethyl-2-methylene bicyclo(3.1.1)heptane |
| (1S,5S)-6,6- | dimethyl-2-methylenebicyclo[3.1.1]heptane |
| (1S,5S)-6,6- | dimethyl-2-methylidenebicyclo[3.1.1]heptane |
| (1S,5S)-7,7- | dimethyl-4-methylidenebicyclo[3.1.1]heptane |
| (-)- | nopinene |
| (-)- | pin-2(10)-ene |
| (1S,5S)- | pin-2(10)-ene |
| (-)-beta- | pinene |
| (1S)-(-)-beta- | pinene |
| L-beta- | pinene |
| None found yet. Try the PubMed Search. |
